Directing Group Repositioning Strategy Enabled Site- and Enantioselective Addition of Heteroaromatic C-H Bonds to Acyclic Internal Alkenes.
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DOI: 10.1021/jacs.3c00095
Abstract: Despite the notable advances achieved in the Murai-type hydroarylations, highly enantioselective catalytic addition of native (hetero)arenes to internal alkenes remains a prominent challenge. Herein, we report a directing group repositioning strategy, which enables the iridium-catalyzed… read more here.
Keywords: addition; repositioning strategy; group repositioning; internal alkenes ... See more keywords