Computational insights into the S3 transfer reaction: A special case of double group transfer reaction featuring bicyclically delocalized aromatic transition state geometries
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.24844
Abstract: An unusual pericyclic process that involves the intermolecular transfer of thiozone (S3) is computationally described. The process can be considered as a special case of double group transfer reaction whereby the two migrating groups are… read more here.
Keywords: group transfer; transfer reaction; reaction; double group ... See more keywords
Analyzing volatility transmission using group transfer entropy
Sign Up to like & getrecommendations! Published in 2018 at "Energy Economics"
DOI: 10.1016/j.eneco.2018.08.008
Abstract: We analyze the transmission of volatility between the oil, stock, gold, and currency markets using transfer entropy. Our approach, which we denote by group transfer entropy, measures the overall sensitivity of a process to lagged… read more here.
Keywords: transfer entropy; group transfer; volatility; transmission ... See more keywords
Group transfer entropy with an application to cryptocurrencies
Sign Up to like & getrecommendations! Published in 2019 at "Physica A: Statistical Mechanics and its Applications"
DOI: 10.1016/j.physa.2018.10.048
Abstract: Abstract The detection of informational leadership is a core issue in financial market microstructure. We use effective group transfer entropy (EGTE) as a measure for the predictability of a stochastic process using lagged observations on… read more here.
Keywords: group transfer; finance; transfer entropy; application cryptocurrencies ... See more keywords
Photocatalytic Decyanative Radical Addition Based on Cyano Group Transfer Mediated by Amine-Ligated Boryl Radicals.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c02217
Abstract: Herein, we describe a photocatalytic strategy for decyanative hydrofunctionalization of styrenes with α-heteroatom-substituted acetonitriles. This strategy facilitates the generation of α-heteroatom methyl radicals from acetonitriles through cyano group transfer (CGT) enabled by amine-ligated boryl radicals.… read more here.
Keywords: group transfer; boryl radicals; amine ligated; ligated boryl ... See more keywords
Aziridine Group Transfer via Transient N-Aziridinyl Radicals
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c14169
Abstract: Aziridines are the smallest nitrogen-containing heterocycles. Strain-enhanced electrophilicity renders aziridines useful synthetic intermediates and gives rise to biological activity. Classical aziridine syntheses—based on either [2 + 1] cycloadditions or intramolecular substitution chemistry—assemble aziridines from acyclic… read more here.
Keywords: group transfer; chemistry; aziridine group; aziridinyl radicals ... See more keywords
Dual-Functional Group Transfer Reagents for Dihalogenation Reactions
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DOI: 10.1055/s-0043-1775497
Abstract: Functional group transfer reagents (FGTRs) represent a powerful strategy for introducing diverse functionalities into organic molecules. Herein, we describe the development and application of novel dual-functional group transfer reagents designed to facilitate efficient and selective… read more here.
Keywords: group transfer; functional group; transfer reagents; dual functional ... See more keywords
Theoretical Study on the Chemical Reactivity in the Armchair Single-walled Carbon Nanotube: Proton and Methyl Group Transfer
Sign Up to like & getrecommendations! Published in 2017 at "Physical Chemistry Research"
DOI: 10.22036/pcr.2017.40717
Abstract: Proton transfer (PT) and methyl group transfer (MGT) occurring in small biomimetic systems, Formamide-Formamidic acid (FA-FI), and N-formyl-N-methylformamide-(E)-methyl N-formylformimidate (NMFA-NMFI) are investigated in the gas phase and in single-walled carbon nanotubes by using the density… read more here.
Keywords: methyl; methyl group; walled carbon; proton ... See more keywords