A computational study of structures and catalytic activities of Hoveyda-Grubbs analogues bearing coumarin or isopropoxycoumarin moiety
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2016.12.014
Abstract: Abstract The DFT/M06-D3 method was used to investigate structures and activation free energies for a series of Hoveyda-Grubbs-like catalysts with the isopropoxybenzene part replaced by coumarin (2H-chromen-2-one) and ten derivatives of isopropoxycoumarin. Out of ten… read more here.
Keywords: structures catalytic; study structures; hoveyda grubbs; computational study ... See more keywords
On Tail Dependence for Three-parameter Grubbs' Copula
Sign Up to like & getrecommendations! Published in 2020 at "Russian Mathematics"
DOI: 10.3103/s1066369x20120063
Abstract: We consider one-sided Grubbs's statistics for a normal sample of the size n. These statistics are extreme studentized deviations of the observations from the sample mean. One abnormal observation (outlier) is assumed in the sample,… read more here.
Keywords: dependence; three parameter; parameter grubbs; grubbs copula ... See more keywords
Unprecedented Multifunctionality of Grubbs and Hoveyda–Grubbs Catalysts: Competitive Isomerization, Hydrogenation, Silylation and Metathesis Occurring in Solution and on Solid Phase
Sign Up to like & getrecommendations! Published in 2017 at "Catalysts"
DOI: 10.3390/catal7040111
Abstract: This contribution showcases the interplay of several non-metathetic reactions (isomerization, silylation and “hydrogen-free” reduction) with metathesis in systems comprising a functionalized olefin and a soluble or resin-immobilized silane. These competing, one-pot reactions occur under activation… read more here.
Keywords: silylation; unprecedented multifunctionality; solid phase; grubbs ... See more keywords