Successful Cyclopolymerization of 1,6-Heptadiynes Using First-Generation Grubbs Catalyst Twenty Years after Its Invention: Revealing a Comprehensive Picture of Cyclopolymerization Using Grubbs Catalysts
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DOI: 10.1021/acs.macromol.7b00488
Abstract: Cyclopolymerization (CP) of 1,6-heptadiynes using olefin metathesis catalysts is a useful method for producing various conjugated polyenes. Unfortunately, commercially available user-friendly Grubbs catalysts have long been known to be inactive toward CP. However, recent mechanistic… read more here.
Keywords: cyclopolymerization; generation grubbs; grubbs catalysts; grubbs catalyst ... See more keywords
In situ analysis and real-time monitoring of the decomposition of the 2nd Grubbs catalyst in CH3CN by droplet spray ionization tandem mass spectrometry
Sign Up to like & getrecommendations! Published in 2017 at "Analytical Methods"
DOI: 10.1039/c7ay01150d
Abstract: The 2nd Grubbs catalysts are widely used in areas of organic and polymer synthesis. However, relatively little data on the decomposition of the 2nd Grubbs catalysts are available. In this work, in situ analysis and… read more here.
Keywords: grubbs catalyst; decomposition; 2nd grubbs; decomposition 2nd ... See more keywords