113Cd as a Probe in NMR Studies of Allosteric Host‐Guest‐Ligand Complexes of Porphyrin Cage Compounds
Sign Up to like & getrecommendations! Published in 2022 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202200111
Abstract: Abstract Cadmium porphyrin cage compounds Cd1 and 113 Cd1 have been synthesized from the free base porphyrin cage derivative H21 and Cd(OAc)2 ⋅ 2 H2O or 113Cd(OAc)2 ⋅ 2 H2O, respectively. The compounds form allosteric complexes with the positively… read more here.
Keywords: porphyrin cage; cage; cage compounds; guest ... See more keywords
Structure and stability of the sH binary hydrate cavity and host‐guest versus guest‐guest interactions therein: A DFT approach
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.27102
Abstract: The intrinsic ability of clathrate hydrates to encage gaseous molecules is explored. Encapsulation ability depends on the cavity size and the type of guest gaseous species in addition to the physical parameters, temperature and pressure.… read more here.
Keywords: cavity; host guest; guest guest; guest ... See more keywords
Electrochemical sensing of N-phenyl-1-naphthylamine using the MWCNT/β-CD through ‘host scavenger–guest pollutant’ mechanism
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Papers"
DOI: 10.1007/s11696-020-01394-w
Abstract: In this report, the synergistic effect of MWCNTs and β-cyclodextrin (β-CD) on glassy carbon electrode (GCE) for the electrochemical sensing of N-Phenylnaphthalen-1-amine (NPN) is demonstrated. The dual role of β-CD (i) as a modifier for… read more here.
Keywords: sensing phenyl; naphthylamine using; electrochemical sensing; host ... See more keywords
Starch inclusion complex for the encapsulation and controlled release of bioactive guest compounds.
Sign Up to like & getrecommendations! Published in 2021 at "Carbohydrate polymers"
DOI: 10.1016/j.carbpol.2021.118596
Abstract: The linear component of starch, especially amylose, is capable of forming inclusion complex (IC) with various small molecules. It could significantly modify the structure and properties of starch, and it could bring beneficial effects when… read more here.
Keywords: encapsulation controlled; controlled release; guest compounds; release ... See more keywords
Self-assembly of β-cyclodextrin-derived amphiphile with a photo responsive guest
Sign Up to like & getrecommendations! Published in 2019 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"
DOI: 10.1016/j.colsurfa.2019.123683
Abstract: Abstract Herein, a photo-responsive mono-component self-assembly system based on host-guest inclusion complexation is presented. An azobenzene group was linked to a β-cyclodextrin by an alkyl chain, generating a novel amphiphile βCD-C6-Azo. The prepared βCD-C6-Azo molecules… read more here.
Keywords: photo responsive; photo; self assembly; assembly cyclodextrin ... See more keywords
A Mg-CP with in Situ Encapsulated Photochromic Guest as Sensitive Fluorescence Sensor for Fe3+/Cr3+ Ions and Nitro-Explosives.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00505
Abstract: Here we report a fluorescent magnesium coordination polymer (Mg-CP), namely, [CH3-dpb]2[Mg3(1,4-NDC)4(μ-H2O)2(CH3OH)(H2O)]·1.5H2O (1, 1,4-H2NDC = 1,4-naphthalene dicarboxylic acid, dpb = 1,4-bis(pyrid-4-yl)benzene). Compound 1 possesses a three-dimensional (3D) host-guest structure constructed by the 1,4-NDC linkers bridging the… read more here.
Keywords: ions nitro; dpb; fe3 cr3; guest ... See more keywords
CO2-Switchable Self-Healing Host–Guest Hydrogels
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b02163
Abstract: The use of natural compounds to construct reversible networks is an attractive strategy in biomaterials design. Our design is based on a host–guest pair of natural compounds β-cyclodextrin and cholic acid through the use of… read more here.
Keywords: self healing; co2 switchable; host guest; guest ... See more keywords
Triblock-Diblock Composite Nanoassemblies with Sequentially Addressable Host-Guest Properties for Hydrophobics and Hydrophilics.
Sign Up to like & getrecommendations! Published in 2020 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.0c00290
Abstract: Noncovalent encapsulation of multiple guest molecules with distinct physiochemical properties, especially hydrophilic and hydrophobic guests, into a single polymeric nanoassembly is challenging, but would be profoundly beneficial to combination therapeutic delivery strategies. Here, we report… read more here.
Keywords: sequentially addressable; nanoassemblies sequentially; diblock composite; triblock diblock ... See more keywords
Self-Assembly and Molecular Recognition in Water: Tubular Stacking and Guest-Templated Discrete Assembly of Water-Soluble, Shape-Persistent Macrocycles.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b11536
Abstract: Supramolecular chemistry in aqueous media is an area with great fundamental and practical significance. To examine the role of multiple non-covalent interactions in controlled assembling and binding behavior in water, the self-association of five water-soluble… read more here.
Keywords: water; water soluble; spectroscopy; molecular recognition ... See more keywords
A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-24344-w
Abstract: Biomolecular systems show how host–guest binding can induce changes in molecular behavior, which in turn impact the functions of the system. Here we report an artificial host–guest system where dynamic adaptation during guest binding alters… read more here.
Keywords: corannulene; second guest; guest; host second ... See more keywords
Improving LMOF luminescence quantum yield through guest-mediated rigidification
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c9tc05216j
Abstract: Rotation of a specific pyridyl ring in LMOF-236 is locked by loading guest molecules into the MOF's pore, improving quantum yield by nearly 400%–an example of a generalizable strategy for maximizing quantum yield via guest-packing… read more here.
Keywords: lmof luminescence; rigidification; improving lmof; yield ... See more keywords