Guest-dependent pressure induced gate-opening effect enables effective separation of propene and propane in a flexible MOF
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2018.03.163
Abstract: Abstract Propene (C3H6)/propane (C3H8) separation is an important but challenging industrial task. Adsorptive separation using porous materials tends to be an energy- and cost-effective strategy. In this work, a flexible porous MOF named NJU-Bai8 is… read more here.
Keywords: dependent pressure; separation; c3h6 c3h8; pressure induced ... See more keywords
Exploring Guest-Dependent Photoconductivity in a Donor-Containing Metal–Organic Framework
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c11190
Abstract: In this computational study, intercalation of tetracyano acceptor guest molecules in In2(OH2)TBAPy (TBAPy = 1,3,6,8-tetrakis(4-carboxyphenyl)pyrene) is proposed as a strategy to induce photoconduct... read more here.
Keywords: containing metal; exploring guest; guest dependent; dependent photoconductivity ... See more keywords
Guest-dependent single-crystal-to-single-crystal transformations in porous adamantane-bearing macrocycles
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DOI: 10.1039/d0ce01782e
Abstract: An adamantane-bearing macrocycle showed permanent intrinsic porosity and adsorption of small organic compounds in a single-crystal-to-single-crystal fashion. Guest uptake by the porous crystals gave rise to the structural transformation of the supramolecular organic framework, resulting… read more here.
Keywords: single crystal; guest dependent; crystal single; adamantane bearing ... See more keywords
Guest-dependent bond flexibility in UiO-66, a "stable" MOF.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc05895b
Abstract: We report "flexibility constants"-a conceptual analog to metal-ligand stability constants-of UiO-66, the prototypical "stable" MOF, across a wide temperature range in both vacuum and in the presence of typical guest solvents. With these data, we… read more here.
Keywords: guest dependent; mof; stable mof; dependent bond ... See more keywords