Noncovalent-bonded 3D Cd(II) and Zn(II) supramolecular metal-organic frameworks from 3,3′,5,5′-tetramethyl-4,4′-bipyrazole and carboxylates
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DOI: 10.1080/00958972.2021.1888940
Abstract: Abstract The present study pertains to the syntheses and characterizations of four mixed-ligand complexes of Cd(H2Bpz)(L1)2(H2O) (1) (L1 = 2-methyl-2-phenoxypropanoic acid), Zn(H2Bpz)(L2)2 (2) (L2 = m-nitrobenzoate), Cd(H2Bpz)2(L3)2 (3) (L3 = 3,4-(methylenedioxy)benzoate) and [Cd2(H2Bpz)3(L4)2]2·2(THF)0.5·4MeOH·4H2O (4) (L4 = o-phthalate). The resulting… read more here.
Keywords: supramolecular metal; noncovalent bonded; geometry; bonded supramolecular ... See more keywords