Reversible complexation of ammonia by breaking a manganese-manganese bond in a manganese carbonyl ethylenedithiolate complex: a theoretical study of an unusual type of Lewis acid.
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DOI: 10.1039/c8dt04217a
Abstract: The reaction of Mn(CO)5Br with sodium ethylenedithiolate was reported in 1968 to give a dark red binuclear H2C2S2Mn2(CO)6 complex possessing the unusual property of complexing reversibly with ammonia to give a yellow H2C2S2Mn2(CO)6·NH3 adduct. In… read more here.
Keywords: bond; complexation; lewis; h2c2s2mn2 ... See more keywords