Cyclometalated complexes containing ferrocenyl Schiff base: Preparation, characterization, DFT calculations, application in cancer and biological researches and MOE studies
Sign Up to like & getrecommendations! Published in 2020 at "Arabian Journal of Chemistry"
DOI: 10.1016/j.arabjc.2020.03.017
Abstract: Abstract A series of transition metal (II/III) complexes containing organometallic Schiff base ligand (H2L) had been synthesized and characterized by using elemental analysis (C, H, N, M), molar conductivity, IR, UV–Vis, 1H NMR and mass… read more here.
Keywords: dft calculations; complexes containing; h2l; ligand ... See more keywords
Interconversion of lanthanide-organic frameworks based on the anions of 2,5-dihydroxyterephthalic acid as connectors
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.05.036
Abstract: Abstract The reaction of a lanthanide precursor with 2,5-dihydroxyterephthalic acid (H4L) yields different MOFs, having [H2L]2− and [L]4− as anionic spacers, in different synthetic conditions. The interconversion conditions have been established for some of them.… read more here.
Keywords: h2l; dihydroxyterephthalic acid; dmf; gd2 h2l ... See more keywords
Fused hexacyclic organotin(IV) compounds derived from 3-[((2-hydroxynaphthalen-1-yl)methylene)amino]naphthalen-2-ol
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130807
Abstract: Abstract The ligand E-3-[((2-hydroxynaphthalen-1-yl)methylene)amino]naphthalen-2-ol (H2L) and its organotin(IV) complexes (Me)2Sn(H2L) (1a), (n-Bu)2Sn(H2L) (1b), (Ph)2Sn(H2L) (1c), (n-Oct)2Sn(H2L) (1d), (Cy)2Sn(H2L) (1e), and (Me3SiCH2)2Sn(H2L) (1f)] have been synthesized in one pot by multicomponent reactions in moderate yields from… read more here.
Keywords: h2l; amino naphthalen; 2sn h2l; methylene amino ... See more keywords
Two Synthetic Approaches to Coinage Metal(I) Mesocates: Electrochemical versus Chemical Synthesis
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02243
Abstract: We report two different approaches to isolate neutral and cationic mesocate-type metallosupramolecular architectures derived from coinage monovalent ions. For this purpose, we use a thiocarbohydrazone ligand, H2L (1), conveniently tuned with bulky phosphine groups to… read more here.
Keywords: two synthetic; h2l; synthetic approaches; approaches coinage ... See more keywords
Photophysical properties of a D-π-A Schiff base and its applications in the detection of metal ions.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03179g
Abstract: A D-π-A Schiff-base compound, 2-amino-3({[4-(diethylamino)-2-hydroxylphenyl]methylene}amino)-but-2-enedinitrile (H2L), was prepared using diaminomaleonitrile and 4-(N,N-diethylamino)salicylaldehyde. Compared with H2L at 293 K, a low temperature of 100 K makes the parallel aromatics in H2L come closer and fluorescence emission… read more here.
Keywords: detection; cul complex; h2l; schiff base ... See more keywords
Structural and Photophysical Properties of 2,1,3-Benzothiadiazole-Based Phosph(III)azane and Its Complexes
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25102428
Abstract: Here we describe the synthesis of a novel N,N’-bis(2,1,3-benzothiadiazol-4-yl)-1-phenylphosphanediamine (H2L) and its zinc (II) and copper (I) coordination compounds [Zn2L2]·nC7H8 (1·nC7H8), [Zn2(H2L)2Cl4]·nC7H8 (2·nC7H8), and [Cu(H2L)Cl]n·nTHF (3·THF). According to single crystal X-ray diffraction analysis, H2L ligand… read more here.
Keywords: based phosph; properties benzothiadiazole; benzothiadiazole based; h2l ... See more keywords