Anion-Dependent Assembly of Heterometallic 3d-4f Clusters Based on a Lacunary Polyoxometalate.
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DOI: 10.1021/acs.inorgchem.7b01104
Abstract: A series of heterometallic 3d-4f clusters, formulated as Na17[Ln3(H2O)5NiII(H2O)3(Sb4O4)(SbW9O33)3(NiIIW6O24)(WO2)3(CH3COO)]·(H2O)65 [abbreviated as Ln3Ni2, where Ln = La3+ (1), Pr3+ (2), and Nd3+ (3)], K5Na11[Ln3(H2O)3NiII3(H2O)6(SbW9O33)3(WO4)(CO3)]·(H2O)40 [abbreviated as Ln3Ni3, where Ln = La3+ (4), Pr3+ (5), and Nd3+… read more here.
Keywords: anion dependent; h2o; heterometallic clusters; h2o abbreviated ... See more keywords