Fluorescent Probes with Variable Intramolecular Charge Transfer: Constructing Closed-Circle Plots for Distinguishing D2O from H2O.
Sign Up to like & getrecommendations! Published in 2023 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.3c00157
Abstract: It is difficult to distinguish between H2O and D2O due to their very similar properties. Triphenylimidazole derivatives with carboxyl groups (TPI-COOH-2R) show intramolecular charge transfer that responds to polarities and pH of solvents. Here, a… read more here.
Keywords: h2o d2o; intramolecular charge; d2o h2o; d2o ... See more keywords
Isotope Effect between H2O and D2O in Hydrothermal Synthesis
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.9b04121
Abstract: Synthetic chemists can use different solvents (for example, polar vs nonpolar) to affect solute–solvent interactions and therefore favor a particular reaction product. Using a different isotope of the same solvent to select the product, however,… read more here.
Keywords: effect h2o; h2o; h2o d2o; isotope effect ... See more keywords