On the Reduction of O2 on Cathode Surfaces of Co–Corrin and Co–Porphyrin: A Computational and Experimental Study on Their Relative Efficiencies in H2O/H2O2 Formation
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c00481
Abstract: The mechanisms for O2 reduction and H2O/H2O2 formation on Co–corrin and Co–porphyrin cathode surfaces of the proton exchange membrane fuel cell (PEMFC) systems have been studied by hybrid Hartree–F... read more here.
Keywords: corrin porphyrin; reduction; cathode surfaces; h2o h2o2 ... See more keywords
Unifying Concepts in Electro- and Thermocatalysis toward Hydrogen Peroxide Production.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c13399
Abstract: We examine relationships between H2O2 and H2O formation on metal nanoparticles by the electrochemical oxygen reduction reaction (ORR) and the thermochemical direct synthesis of H2O2. The similar mechanisms of such reactions suggest that these catalysts… read more here.
Keywords: thermocatalysis; concepts electro; formation; h2o2 ... See more keywords
Bimetallic core-based cuboctahedral core-shell nanoclusters for the formation of hydrogen peroxide (2e- reduction) over water (4e- reduction): role of core metals.
Sign Up to like & getrecommendations! Published in 2017 at "Nanoscale"
DOI: 10.1039/c7nr03002a
Abstract: The design of an efficient and selective catalyst for hydrogen peroxide (H2O2) formation is highly sought due to its industrial importance. As alternatives to a conventional Pd-Au alloy-based catalyst, three cuboctahedral core-shell nanoclusters (Au19@Pt60, Co19@Pt60… read more here.
Keywords: reduction; core shell; formation; au10co9 pt60 ... See more keywords