Cooperative Electrocatalytic O2 Reduction Involving Co(salophen) with p-Hydroquinone as an Electron-Proton Transfer Mediator.
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DOI: 10.1021/jacs.7b11362
Abstract: The molecular cobalt complex, Co(salophen), and para-hydroquinone (H2Q) serve as effective cocatalysts for the electrochemical reduction of O2 to water. Mechanistic studies reveal redox cooperativity between Co(salophen) and H2Q. H2Q serves as an electron-proton transfer… read more here.
Keywords: reduction; salophen; proton transfer; transfer mediator ... See more keywords