Dehydropolymerization of H3B·NMeH2 Using a [Rh(DPEphos)]+ Catalyst: The Promoting Effect of NMeH2
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DOI: 10.1021/acscatal.9b00081
Abstract: [Rh(κ2-PP-DPEphos){η2η2-H2B(NMe3)(CH2)2tBu}][BArF4] acts as an effective precatalyst for the dehydropolymerization of H3B·NMeH2 to form N-methylpolyaminoborane (H2BNMeH)n. Control of polymer molecular weight is achieved by variation of precatalyst loading (0.1–1 mol %, an inverse relationship) and use… read more here.
Keywords: dehydropolymerization h3b; precatalyst; h3b nmeh2; dpephos ... See more keywords