Preparation of double decker {Li3(Cl−)(Hhp)}22− dianions and H2TPCor− monoanions by deprotonation of free-base trithiododecaazahexaphyrin (H3Hhp) and triphenylcorrole (H3TPCor) macrocycles
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DOI: 10.1016/j.poly.2021.115198
Abstract: Abstract Deprotonation of free-base [30]trithia-2,3,5,10,12,13,15,20,22,23,25,30-dodecaazahexaphyrin (hemihexaphyrazine, H3Hhp) and 5, 10, 15- triphenylcorrole (H3TPCor) macrocycles by an excess of lithium diethylamide, LiNEt2, in the presence of three equivalents of cryptand[2.2.2] has been studied. Crystallization of the… read more here.
Keywords: free base; h3hhp triphenylcorrole; hhp; deprotonation free ... See more keywords