Synthesis, Characterization, and Polymorphism of [H3O][NbF6]: A Polar and Possibly Ferroelectric Oxonium Salt
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400015
Abstract: [H3O][NbF6] was obtained from the controlled hydrolysis of NbF5 in anhydrous liquid HF. It adopts a polar, orthorhombic crystal structure with space group Iba2 (no. 45, oI88) at room temperature. A first‐order phase transition at… read more here.
Keywords: temperature; space group; h3o nbf6; h3o ... See more keywords
The effect of H3O+ on the membrane morphology and hydrogen bonding of a phospholipid bilayer
Sign Up to like & getrecommendations! Published in 2018 at "Biophysical Reviews"
DOI: 10.1007/s12551-018-0454-z
Abstract: At the 2017 meeting of the Australian Society for Biophysics, we presented the combined results from two recent studies showing how hydronium ions (H3O+) modulate the structure and ion permeability of phospholipid bilayers. In the… read more here.
Keywords: h3o; effect; bilayer; hydrogen bonding ... See more keywords
On the solvation of hydronium by carbon dioxide: Structural and infrared spectroscopic study of (H 3 O + )(CO 2 ) n
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Physics"
DOI: 10.1016/j.chemphys.2017.11.015
Abstract: Abstract Hydronium (H3O+) is the smallest member of protonated water. In this work, we use quantum chemical calculations to explore the solvation of H3O+ by adding one CO2 molecule at a time. The effect of… read more here.
Keywords: carbon dioxide; solvation hydronium; h3o; solvation ... See more keywords
Protonation of calix[4]arene-(2,3-naphthylene-crown-6,crown-6): Experimental and theoretical study
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DOI: 10.1016/j.molstruc.2016.12.013
Abstract: Abstract On the basis of extraction experiments and γ-activity measurements, the extraction constant corresponding to the equilibrium H3O+ (aq) + 1·Na+ (nb) ⇄ 1·H3O+ (nb) + Na+ (aq) occurring in the two–phase water–nitrobenzene system (1 = calix[4]arene-(2,3-naphthylene-crown-6,crown-6); aq = aqueous phase, nb = nitrobenzene phase)… read more here.
Keywords: calix arene; protonation calix; arene naphthylene; naphthylene crown ... See more keywords
(H3O)Li2(IO3)3: crystal structure and IR spectrum
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Instrumentation"
DOI: 10.1088/1748-0221/19/04/c04018
Abstract: The synthesis, IR spectroscopy, thermal and UV-Vis transmittance of the new lithium iodate crystal: (H3O)Li2(IO3)3, were studied. The crystal structure of (H3O)+·2(Li)+· 3(IO3)- was determined by single-crystal X-Ray diffraction analysis at 100(2) K. It crystallizes… read more here.
Keywords: crystal structure; structure; h3o; li2 io3 ... See more keywords