Three-Electron Nickel(I)/Nickel(0) Half-Bond.
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DOI: 10.1021/acs.inorgchem.2c02291
Abstract: An (N-heterocyclic carbene)nickel(I) cation precursor reacts with the corresponding nickel(0) complex to form a dinickel(I,0) monocation. The Ni···Ni distance in this cation is 0.93 Å shorter than in the analogous dinickel(0) complex. Although the solid-state… read more here.
Keywords: half bond; chemistry; electron nickel; nickel half ... See more keywords