Half-Lantern Binuclear Pt(II) Complexes with Heteroleptic Cyclometalated 2-Phenylpyridine Ligands: Synthesis, Metal-Induced Planar Chirality, Chirality Self-Sorting, and Chiroptical Properties.
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DOI: 10.1021/acs.orglett.5c01835
Abstract: Half-lantern binuclear Pt(II) complexes bearing two heteroleptic cyclometalated 2-phenylpyridine ligands were synthesized and characterized for the first time. Heteroleptic cyclometalation is favorable for achieving an asymmetric charge distribution and for tuning optical properties. The maximum… read more here.
Keywords: binuclear complexes; heteroleptic cyclometalated; lantern binuclear; half lantern ... See more keywords