Halide-Accelerated Acyl Fluoride Formation Using Sulfuryl Fluoride.
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DOI: 10.1021/acs.orglett.0c02566
Abstract: Herein, we report a new one-pot sequential method for SO2F2-mediated nucleophilic acyl substitution reactions starting from carboxylic acids. A mechanistic study revealed that SO2F2-mediated acid activation proceeds via the anhydride, which is then converted to… read more here.
Keywords: halide accelerated; fluoride formation; acyl fluoride; accelerated acyl ... See more keywords