Luminescence Quenching of Ligand‐Substituted Molybdenum and Tungsten Halide Clusters by Oxygen and Their Oxidation Electrochemistry
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700763
Abstract: Cluster compounds (TBA)2[Mo6I8(CF3SO3)6], (TBA)2[W6I8(CF3SO3)6], and (TBA)2[W6Br8(CF3SO3)6] are prepared and structurally characterized from single-crystal X-ray diffraction data. All compounds show red emission on photoexcitation at 400 nm. However, the phosphorescence of crystalline samples is quenched in… read more here.
Keywords: quenching ligand; luminescence quenching; halide clusters; ligand substituted ... See more keywords
Hydrated halide clusters on electrode materials for aqueous supercapacitor
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Power Sources"
DOI: 10.1016/j.jpowsour.2021.229612
Abstract: Abstract We develop a novel film electrode fabrication technology involving phase separation and self-assemble of hydrophilic and hydrophobic polymers together with the active materials, and introducing different halide ions into membrane. With the introduction of… read more here.
Keywords: electrode materials; materials aqueous; halide clusters; aqueous supercapacitor ... See more keywords
A new type of composite MOFs based on high-valent Sb(v)-based units and cuprous-halide clusters.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc08443f
Abstract: An unusual high-valent Sb(v)-based unit [SbL2]- (L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) was developed for the first time to combine with various cuprous-halide clusters for the construction of a brand-new class of heterometallic MOFs. This work not only… read more here.
Keywords: cuprous halide; valent based; high valent; halide clusters ... See more keywords