Rhoda- and iridacarborane halide complexes: Synthesis, structure and application in homogeneous catalysis
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121135
Abstract: Abstract The review covers the synthesis, structural features and catalytic activity of rhoda- and iridacarborane halide complexes containing monoanionic dicarbollide [L-C2B9H10]− (L = SMe2, NMe3) and tricarbollide [tBuHN-C3B8H10]− ligands. These complexes are structural analogs of the well-known… read more here.
Keywords: rhoda iridacarborane; iridacarborane halide; halide complexes; structure ... See more keywords
Cobalt and zinc halide complexes of 4-chloro and 4-methylaniline: Syntheses, structures and magnetic behavior
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.04.025
Abstract: Abstract A family of cobalt(II) and zinc(II) compounds with the general formula (4-subC6H4NH2)2MX2, (M = Co, Zn; X = Cl, Br; sub = CH3, Cl) has been prepared and the compounds characterized by single-crystal X-ray diffraction. The eight compounds crystallize in… read more here.
Keywords: cobalt; halide complexes; complexes chloro; zinc halide ... See more keywords
A new strategy to synthesize three-coordinate mononuclear copper(i) halide complexes containing a bulky terphenyl bidentate phosphine ligand and their luminescent properties
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c8nj05605f
Abstract: Three mononuclear three-coordinate Cu(i) halide complexes were synthesized by a new strategy and they exhibit green to yellow green emission in the solid state at room temperature. read more here.
Keywords: new strategy; halide complexes; three coordinate;
From deep blue to green emitting and ultralong fluorescent copper(i) halide complexes containing dimethylthiophene diphosphine and PPh3 ligands.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01548e
Abstract: Highly emissive copper(i) halide complexes having thermally activated delayed fluorescence (TADF) have been paid much attention. Here, a series of four-coordinate mononuclear copper(i) halide complexes containing both bi- and mono-phosphine ligands, [CuX(dpmt)(PPh3)] (dpmt = 3,4-bis(diphenylphosphino)-2,5-dimethylthiophene,… read more here.
Keywords: deep blue; copper halide; halide complexes; complexes containing ... See more keywords
New Cu(i) halide complexes showing TADF combined with room temperature phosphorescence: the balance tuned by halogens.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt00192a
Abstract: A series of Cu(i) halide complexes derived from tris(2-pyridyl)phosphine (Py3P), [Cu2(Py3P)2X2] (X = Cl, Br, I), have been synthesized by a straightforward reaction in solution or through a mechanochemical route. At room temperature, the solid… read more here.
Keywords: halide complexes; tadf; cu2 py3p; room temperature ... See more keywords
Magnetic anisotropy of two tetrahedral Co(II)-halide complexes with triphenylphosphine ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00121g
Abstract: Recently, the choice of ligand and geometric control of mononuclear complexes, which can affect the relaxation pathways and blocking temperature, have received wide attention in the field of single-ion magnets (SIMs). To find out the… read more here.
Keywords: two tetrahedral; spectroscopy; halide complexes; magnetic anisotropy ... See more keywords
Recent Progress in Luminescent Cu(I) Halide Complexes: A Mini-Review
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2021.816363
Abstract: Copper(I) halide complexes are well sought-after materials due to their rich structural diversities and photophysical properties. Profoundly, there is a direct relationship between each structural variation and luminescence of these complexes, for a purported use.… read more here.
Keywords: recent progress; halide; progress luminescent; halide complexes ... See more keywords
Structural Diversity of Mercury(II) Halide Complexes Containing Bis-pyridyl-bis-amide with Bulky and Angular Backbones: Ligand Effect and Metal Sensing
Sign Up to like & getrecommendations! Published in 2022 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms23147861
Abstract: Hg(II) halide complexes [HgCl2] 2L1 [L1 = N,N’-bis(3-pyridyl)bicyclo(2,2,2,)oct-7-ene-2,3,5,6-tetracarboxylic diamide), 1, [HgBr2(L1)]n, 2, [HgI2(L1)], 3, [Hg2X4(L2)2] [X = Cl, 4, Br, 5, and I, 6; L2 = N,N’-bis(4-pyridylmethyl)bicyclo(2,2,2,)oct-7-ene-2,3,5,6-tetracarboxylic diamide] and {[HgX2(L3)]⋅H2O}n [X = Cl, 7, Br,… read more here.
Keywords: bis; halide; halide complexes; bis pyridyl ... See more keywords
Zn(II) Heteroleptic Halide Complexes with 2-Halopyridines: Features of Halogen Bonding in Solid State
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26113393
Abstract: Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4),… read more here.
Keywords: state; halide complexes; complexes halopyridines; halogen bonding ... See more keywords
Tris(aminomethyl)phosphines and Their Copper(I) (Pseudo)halide Complexes with Aromatic Diimines—A Critical Retrospection
Sign Up to like & getrecommendations! Published in 2023 at "Pharmaceuticals"
DOI: 10.3390/ph16050766
Abstract: Metal complexes feature a wide range of available geometries, diversified lability, controllable hydrolytic stability, and easily available rich redox activity. These characteristics, combined with the specific properties of coordinated organic molecules, result in many different… read more here.
Keywords: pseudo halide; halide complexes; complexes aromatic; copper pseudo ... See more keywords