Halide‐Free Synthesis of New Difluoro(oxalato)borate [DFOB]−‐Based Ionic Liquids and Organic Ionic Plastic Crystals
Sign Up to like & getrecommendations! Published in 2022 at "Chemphyschem"
DOI: 10.1002/cphc.202200115
Abstract: Abstract The implementation of next‐generation batteries requires the development of safe, compatible electrolytes that are stable and do not cause safety problems. The difluoro(oxalato)borate ([DFOB]−) anion has been used as an electrolyte additive to aid… read more here.
Keywords: halide free; oxalato borate; difluoro oxalato; borate dfob ... See more keywords
Hydrogen halide-free synthesis of organohalides for organometal trihalide perovskite solar cells
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Industrial and Engineering Chemistry"
DOI: 10.1016/j.jiec.2020.06.006
Abstract: Abstract We report an environmentally benign and economical approach for the large-scale production of methylammonium halides (MAX, X = I or Br) and formamidinium halides (FAX, X = I or Br) as core materials in perovskite solar cells (PSCs),… read more here.
Keywords: ion exchange; perovskite solar; hydrogen halide; halide free ... See more keywords
Halide-Free Continuous Synthesis of Hydrophobic Ionic Liquids
Sign Up to like & getrecommendations! Published in 2022 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.2c02871
Abstract: Herein, we present a novel approach for the halide-free, continuous-flow preparation of hydrophobic ionic liquids (ILs) relying on the bis(trifluoromethanesulfonyl)imide (bistriflimide, NTf2–) anion. The simple yet fast two-step synthetic route, which involves the formation of… read more here.
Keywords: halide free; free continuous; ionic liquids; hydrophobic ionic ... See more keywords
Below the 12-vertex: 10-vertex carborane anions as non-corrosive, halide free, electrolytes for rechargeable Mg batteries.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc01570d
Abstract: The development of practical Mg based batteries is limited by the lack of a library of suitable electrolytes. Recently a 12-vertex closo-carborane anion based electrolyte has been shown to be the first electrolyte for Mg… read more here.
Keywords: carborane anions; closo carborane; vertex closo; halide free ... See more keywords
Pursuing unprecedented anisotropic morphologies of halide-free Pd nanoparticles by tuning their nucleation and growth.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01498j
Abstract: In this paper, a highly effective and scalable polyol-based modified procedure is reported, yielding shape-controlled Pd nanoparticles (NPs) formed via two distinct growth mechanisms as a function of apparent pH. Starting from tetraethylammonium tetrahydroxypalladate (TEA)2[Pd(OH)4],… read more here.
Keywords: halide free; anisotropic morphologies; growth; unprecedented anisotropic ... See more keywords
Evaluation of Aqueous Biphasic Electrophoresis System Based on Halide-Free Ionic Liquids for Direct Recovery of Keratinase
Sign Up to like & getrecommendations! Published in 2021 at "Marine Drugs"
DOI: 10.3390/md19080463
Abstract: Aqueous biphasic electrophoresis system (ABES) incorporates electric fields into the biphasic system to separate the target biomolecules from crude feedstock. Ionic liquid (IL) is regarded as an excellent candidate as the phase-forming components for ABES… read more here.
Keywords: recovery; biphasic electrophoresis; aqueous biphasic; system ... See more keywords