Cyclometalated half‐sandwich iridium complexes: Synthesis, characterization, and catalytic activity in preparation of esters from halides by using formate as both CO source and coupling partner
Sign Up to like & getrecommendations! Published in 2024 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.7555
Abstract: A highly efficient carbonylation of aryl halides using half‐sandwich iridium catalysis was developed, providing a new avenue for synthesizing carboxylic ester derivatives and yielding consistently impressive results. These iridium complexes demonstrated remarkable catalytic performance in… read more here.
Keywords: iridium; sandwich iridium; half sandwich; catalytic activity ... See more keywords
Aminomethylation of Aryl Halides using α-Silylamines Enabled by Ni/Photoredox Dual Catalysis.
Sign Up to like & getrecommendations! Published in 2017 at "ACS catalysis"
DOI: 10.1021/acscatal.7b01973
Abstract: A protocol for the aminomethylation of aryl halides using α-silylamines via Ni/photoredox dual catalysis is described. The low oxidation potential of these silylated species enables facile single electron transfer (SET) oxidation of the amine followed… read more here.
Keywords: halides using; aminomethylation; catalysis; aryl halides ... See more keywords
Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra08009c
Abstract: The nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source is developed. The procedure can prepare both tertiary and secondary amides, and is applicable to various carbamoylsilanes and aryl halides containing different functional… read more here.
Keywords: catalyzed aminocarbonylation; halides using; aminocarbonylation aryl; aryl halides ... See more keywords