Aminomethylation of Aryl Halides using α-Silylamines Enabled by Ni/Photoredox Dual Catalysis.
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DOI: 10.1021/acscatal.7b01973
Abstract: A protocol for the aminomethylation of aryl halides using α-silylamines via Ni/photoredox dual catalysis is described. The low oxidation potential of these silylated species enables facile single electron transfer (SET) oxidation of the amine followed… read more here.
Keywords: halides using; aminomethylation; catalysis; aryl halides ... See more keywords
Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source
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DOI: 10.1039/c7ra08009c
Abstract: The nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source is developed. The procedure can prepare both tertiary and secondary amides, and is applicable to various carbamoylsilanes and aryl halides containing different functional… read more here.
Keywords: catalyzed aminocarbonylation; halides using; aminocarbonylation aryl; aryl halides ... See more keywords