LAUSR

Heterobimetallic μ2-halocarbyne complexes.

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1 Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt01558g

Abstract: The halocarbyne complexes [M(CX)(CO)2(Tp*)] (M = Mo, W; X = Cl, Br; Tp* = hydrotris(dimethylpyrazolyl)borate) react with [AuCl(SMe2)], [Pt(η2-H2CCH2)(PPh3)2] or [Pt(η2-nbe)3] (nbe = norbornene) to furnish rare examples of μ2-halocarbyne complexes [MAu(μ2-CX)Cl(CO)2(Tp*)], [MPt(μ2-CCl)(CO)2(PPh3)2(Tp*)] and [W2Pt(μ2-CCl)2(CO)4(Tp*)2].… read more here.

Keywords: halocarbyne; ccl pph3; halocarbyne complexes; wpt ... See more keywords