Through‐Space CBr···π Halogen Interaction: Efficient Modulation of Reaction‐Based Photochromism and Photoluminescence at Crystalline States for Irradiation Time‐Dependent Anti‐Counterfeiting
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202009024
Abstract: Reaction‐based photo‐responsive molecular systems have been used as a reliable platform for building intelligent materials, but often suffer from high inactivity in terms of conversion efficiency and reversibility when it comes to solid‐state applications. Herein,… read more here.
Keywords: photoluminescence; reaction based; solid state; state ... See more keywords
Harnessing Halogen‐Induced Anharmonic Effect to Achieve Low Lattice Thermal Conductivity in High‐Symmetry Cu2SnS3 for High‐Performance Thermoelectric Applications
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202501535
Abstract: While possessing outstanding electrical properties, suppressing the lattice thermal conductivity (κlat) is of great significance for achieving excellent thermoelectric materials. Here, based on optimizing electrical transport by transforming monoclinic Cu2SnS3 into a cubic phase, Halogen… read more here.
Keywords: halogen; lattice thermal; symmetry; performance ... See more keywords
Halogenated Rubber Enables 19.78%‐Efficiency Organic Solar Cells With Enhanced Ductility via Halogen‐Mediated Non‐Covalent Interactions
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202519810
Abstract: The pursuit of 20% power conversion efficiencies (PCEs) in organic solar cells (OSCs) has been remarkably successful, yet their intrinsic mechanical fragility remains a fundamental constraint for flexible applications. In this work, this challenge is… read more here.
Keywords: solar cells; rubber; halogen; organic solar ... See more keywords
Free-Standing Halogen-Bonded Nanosheets Formed by Ultrasonic Liquid Exfoliation.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced science"
DOI: 10.1002/advs.202507800
Abstract: Strong in‐layer interactions are typically considered a key requirement for exfoliating layered materials to form nanosheets. Here, the formation of free‐standing nanosheets held together by halogen bonding interactions is reported for the first time. Layered… read more here.
Keywords: free standing; standing halogen; halogen; bonded nanosheets ... See more keywords
Strategic Halogen Substitution to Enable High‐Performance Small‐Molecule‐Based Tandem Solar Cell with over 15% Efficiency
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DOI: 10.1002/aenm.201903846
Abstract: Small molecules have been recently highlighted as active materials owing to their facile synthesisis method, well‐defined molecular structure, and highly reproducible performance. In particular, optimizing bulk heterojunction (BHJ) morphologies is important to achieving high performance… read more here.
Keywords: high performance; small molecule; performance; halogen ... See more keywords
Halogen Substituents in the Isoquinoline Scaffold Switches the Selectivity of Inhibition between USP2 and USP7
Sign Up to like & getrecommendations! Published in 2019 at "ChemBioChem"
DOI: 10.1002/cbic.201800612
Abstract: Deubiquitinases are important components of the protein regulatory network and, hence, constitute a tempting drug target. We report herein structure–activity relationship studies to develop halogen‐substituted isoquionoline‐1,3‐dione‐based inhibitors of the deubiquitinase USP2. In contrast to our… read more here.
Keywords: switches selectivity; inhibition; halogen substituents; halogen ... See more keywords
Comparison of Anion-Anion Halogen Bonds with Neutral-Anion Halogen Bonds in the Gas Phase and Polar Solvents.
Sign Up to like & getrecommendations! Published in 2021 at "ChemPlusChem"
DOI: 10.1002/cplu.202000734
Abstract: In recent years, anion-anion halogen bonds and neutral-anion halogen bonds have received extensive attention. In this work, the possibility of halogen bonding of neutral and anionic forms of para-substituted iodine derivatives of dithiobenzoic acid and… read more here.
Keywords: anion; anion anion; halogen; gas phase ... See more keywords
Tuning of Ionic Liquid Crystal Properties by Combining Halogen Bonding and Fluorous Effect.
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DOI: 10.1002/cplu.202100046
Abstract: We report halogen-bonded complexes between 1-polyfluoroalkyl-3-alkylimidazolium iodides and mono-iodoperfluoroalkanes of different chain lengths or di-iodoperfluorooctane. 19 F NMR analyses revealed that the preferred stoichiometry between the donors and acceptors is 1 : 1 in the cases of… read more here.
Keywords: ionic liquid; liquid; liquid crystal; halogen ... See more keywords
Aggregation-Induced Electrochemiluminescence and Nitric Oxide Recognition by Halogen Bonding with a Ruthenium(II) Complex.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202200421
Abstract: In this study, a new strategy for NO detection based on the aggregation-induced electrochemical luminescence (AIECL) of a ruthenium-based complex and the halogen bonding effect was developed. First, [Ru(phen)2(phen-Br2)]2+ (phen:1,10-phenanthroline, phen-Br2:3,8-dibromo-1,10-phenanthroline) was synthesized and exhibited aggregation-induced… read more here.
Keywords: halogen; phen; aggregation induced; halogen bonding ... See more keywords
Effect of π–π Interactions on Morphology of Nonplanar Binary Halogen‐Bonded Cocrystals
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DOI: 10.1002/crat.202300315
Abstract: The application of organic crystal in different photoelectric device has different demand on the crystal structure and morphology, while the self‐assembly of different materials into crystals with a desired morphology remains a challenge. Herein, using… read more here.
Keywords: binary halogen; bonded cocrystals; nonplanar binary; halogen ... See more keywords
Halogen Bonds in Square Planar 2,5‐Dihalopyridine–Copper(II) Bromide Complexes
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201800144
Abstract: Halogen bonding in self-complementary 1:2 metal-ligand complexes obtained from copper(II) bromide (CuBr2) and seven 2,5dihalopyridines are analyzed using single crystal X-ray diffraction. All presented discrete complexes form 1-D polymeric chains connected with C–X···Br–Cu halogen bonds… read more here.
Keywords: bonds square; copper bromide; square planar; halogen ... See more keywords