Interplay of halogen and hydrogen bonding in a series of heteroleptic iron(iii) complexes
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DOI: 10.1039/d1ce00480h
Abstract: The influence of the halogen substituent on crystal packing and redox properties is investigated in a series of heteroleptic complexes [Fe(qsal-X)(dipic)]·MeOH (qsal-X = 4-halogen-2-[(8-quinolylimino)methyl]phenolate; dipic = 2,6-pyridinedicarboxylate; X = F 1, Cl 2, Br 3… read more here.
Keywords: interplay halogen; series heteroleptic; halogen; halogen hydrogen ... See more keywords
Exploring Orthogonality between Halogen and Hydrogen Bonding Involving Benzene
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DOI: 10.3390/molecules26237126
Abstract: The concept of orthogonality between halogen and hydrogen bonding, brought out by Ho and coworkers some years ago, has become a widely accepted idea within the chemists’ community. While the original work was based on… read more here.
Keywords: orthogonality halogen; hydrogen bonding; halogen hydrogen;
Thermodynamics and Spectroscopy of Halogen- and Hydrogen-Bonded Complexes of Haloforms with Aromatic and Aliphatic Amines
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DOI: 10.3390/molecules27186124
Abstract: Similarities and differences of halogen and hydrogen bonding were explored via UV–Vis and 1H NMR measurements, X-ray crystallography and computational analysis of the associations of CHX3 (X=I, Br, Cl) with aromatic (tetramethyl-p-phenylenediamine) and aliphatic (4-diazabicyclo[2,2,2]octane)… read more here.
Keywords: spectroscopy; thermodynamics; hydrogen; bonded complexes ... See more keywords