Versatile halogenation via a CNHC^Csp3 palladacycle intermediate.
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DOI: 10.1039/d3dt00113j
Abstract: Stable cyclopalladated complexes containing an (sp3)C-Pd bond were synthesized via α-CH2 deprotonation and palladation of N-alkyl groups of carbene ligands bearing electron-withdrawing substituents. The strong electron donating strengths of the resulting CNHC^Csp3 chelators were experimentally… read more here.
Keywords: cnhc csp3; palladacycle; halogenation via; versatile halogenation ... See more keywords