Extending the Hammett correlation to mechanochemical reactions.
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DOI: 10.1039/d2cc06487a
Abstract: Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge… read more here.
Keywords: mechanochemical reactions; extending hammett; chemistry; correlation mechanochemical ... See more keywords