Synthesis of gem-Disulfonyl Enamines via an Iminyl-Radical-Mediated Formal 1,3-HAT/Radical Coupling Cascade.
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DOI: 10.1021/acs.orglett.2c02277
Abstract: We herein report the first example of an iminyl-radical-mediated formal 1,3-HAT/radical coupling cascade of vinyl azides leading to the synthesis of tetrasubstituted gem-disulfonyl enamines. It is possible to employ a variety of vinyl azides and… read more here.
Keywords: mediated formal; iminyl radical; hat radical; radical coupling ... See more keywords