Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin.
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DOI: 10.1021/acs.orglett.0c01168
Abstract: Simple nucleophiles with structural similarities to known hydroboration catalysts can readily mediate the formation of BH3 and borohydride species from pinacolborane (HBpin). Alkyne and alkene hydroboration reactions were successfully mediated by nucleophiles through BH3 generation,… read more here.
Keywords: boron catalysis; hbpin; hidden boron; catalysis nucleophile ... See more keywords