Comprehensive theoretical analysis of the influence of surface alloying by zinc on the catalytic performance of Cu(1 1 0) for the production of methanol from CO2 selective hydrogenation: Part 1 – Thermochemical aspects
Sign Up to like & getrecommendations! Published in 2019 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2018.11.038
Abstract: Abstract Open copper facets such as Cu(1 1 0) were recently reported to most likely act as an active center of commercial Cu/ZnO/Al2O3 methanol synthesis catalysts. Surprisingly, unlike other surfaces of the metal component, the Cu(1 1 0) facet… read more here.
Keywords: hcoo; surface; catalytic performance; production ... See more keywords
The mechanisms of HCOOH/HCOO– oxidation on Pt electrodes: Implication from the pH effect and H/D kinetic isotope effect
Sign Up to like & getrecommendations! Published in 2017 at "Electrochemistry Communications"
DOI: 10.1016/j.elecom.2017.05.012
Abstract: Abstract The pH effect and the H/D kinetic isotope effect (KIE) for the oxidation of formic acid/formate anions (FOR) on Pt(111) have been studied. The pH-dependent FOR activity displays a volcano shape with a maximum… read more here.
Keywords: effect; isotope effect; hcooh hcoo; hcoo ... See more keywords
Highly Dispersed Few-Nanometer Chlorine-Doped SnO2 Catalyst Embedded in a Polyaniline Matrix for Stable HCOO– Production in a Flow Cell
Sign Up to like & getrecommendations! Published in 2022 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.2c12428
Abstract: With the spread of alternative energy plants, electrolysis processes are becoming the protagonists of the future industrial generation. The technology readiness level for the electrochemical reduction of carbon dioxide is still low and is largely… read more here.
Keywords: chlorine doped; catalyst; polyaniline matrix; hcoo ... See more keywords
DFT Modeling of CO2 Adsorption and HCOO• Group Conversion in Anatase Au-TiO2-Based Photocatalysis
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c06861
Abstract: Due to the merits of carbon circulation and hydrocarbon production, solar-assisted photocatalysis has been regarded as an ideal option for securing a sustainable future of energy and environment. In the photocatalytic carbon cycle process, surface… read more here.
Keywords: adsorption; co2 adsorption; photocatalysis; conversion ... See more keywords
Efflorescence on calcareous objects in museums: crystallisation, phase characterisation and crystal structures of calcium acetate formate phases.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03558c
Abstract: During the systematic investigation of the ternary system Ca(CH3COO)2-Ca(HCOO)2-H2O at room temperature, the congruent crystallisation of two solid calcium acetate formates was observed: the hitherto unknown Ca3(CH3COO)4(HCOO)2·4H2O and the poorly characterised Ca(CH3COO)(HCOO)·H2O. The latter is… read more here.
Keywords: phase; ch3coo hcoo; hcoo h2o; crystal structures ... See more keywords
Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry frontiers"
DOI: 10.1039/c9qi01263j
Abstract: A simple binary synthetic approach with variable [HCOOH]/[Th(IV)] ratios and the addition of water resulted in the self-assembly of six novel thorium formate complexes with well-controlled structures ranging from 0D clusters and 2D layered networks… read more here.
Keywords: thorium; h2o; hcoo; dmf h2o ... See more keywords
Mechanism and Selectivity of Electrochemical Reduction of CO2 on Metalloporphyrin Catalysts from DFT Studies
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28010375
Abstract: Electrochemical reduction of CO2 to value-added chemicals has been hindered by poor product selectivity and competition from hydrogen evolution reactions. This study aims to unravel the origin of the product selectivity and competitive hydrogen evolution… read more here.
Keywords: product selectivity; reduction co2; hcoo; electrochemical reduction ... See more keywords