Synthesis of nano magnetic supported NHC-palladium and investigation of its applications as a catalyst in the Mizoroki-Heck cross-coupling reaction in H2O
Sign Up to like & getrecommendations! Published in 2020 at "Heliyon"
DOI: 10.1016/j.heliyon.2020.e04946
Abstract: The unique properties of N-heterocyclic carbenes (NHCs) as an effective ligand for palladium catalytic centers have recently found much attention. In this work, Fe3O4 nanoparticle supported palladium(II)–N-heterocyclic carbene catalyst was successfully designed, synthesized and characterized… read more here.
Keywords: coupling reaction; cross coupling; heck cross; reaction ... See more keywords
A palladium thiolate-SNS complex-catalyst for Mizoroki-Heck cross-coupling.
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DOI: 10.1039/d5dt01008j
Abstract: Phosphine-free catalysts for the Mizoroki-Heck cross-coupling reaction offer significant advantages in terms of air and moisture stability. We synthesized two palladium(II) complexes featuring a thiolate-imine-thioether SNS pincer ligand: Pd(κ2-SNSMe)2 (Pd-1) and PdI(κ3-SNSMe) (Pd-2). Their catalytic… read more here.
Keywords: sns; mizoroki heck; cross coupling; heck cross ... See more keywords
Synthesis of Bio-Inspired 1,3-Diarylpropene Derivatives via Heck Cross-Coupling and Cytotoxic Evaluation on Breast Cancer Cells
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DOI: 10.3390/molecules27175373
Abstract: The Heck cross-coupling reaction is a well-established chemical tool for the synthesis of unsaturated compounds by formation of a new C-C bond. In this study, 1,3-diarylpropene derivatives, designed as structural analogues of stilbenoids and dihydrostilbenoids,… read more here.
Keywords: cross coupling; heck cross; breast cancer; cancer cells ... See more keywords