Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction
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DOI: 10.1039/d2ra00078d
Abstract: For the first time we describe a general method for the synthesis of previously not synthesized unsymmetrical 3,4-diarylbutadiene sulfones which can be stable convenient precursors for 2,3-diaryl-1,3-butadienes. Our method for arylation of butadiene sulfones via… read more here.
Keywords: diarylbutadiene; matsuda reaction; heck matsuda; diarylbutadiene sulfones ... See more keywords
A regio- and stereoselective Heck–Matsuda process for construction of γ-aryl allylsulfonyl fluorides
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DOI: 10.1039/d2ra03733e
Abstract: A highly efficient regio- and stereoselective Heck–Matsuda method was developed employing aryl diazoniums and allylsulfonyl fluorides for the construction of a class of novel γ-aryl allylsulfonyl fluorides in the presence of Pd(OAc)2 and PPh3. The… read more here.
Keywords: heck matsuda; aryl allylsulfonyl; allylsulfonyl fluorides; regio stereoselective ... See more keywords
Highly diastereoselective Heck–Matsuda reaction with pyrazolyl diazonium salts
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DOI: 10.1039/d3nj01724a
Abstract: Novel pyrazolyl-derived diazonium tetrafluoroborate salts were used in the palladium-catalyzed Heck–Matsuda reaction for the diastereoselective synthesis of highly substituted cyclopenten-ols/-amines. read more here.
Keywords: heck matsuda; pyrazolyl; matsuda reaction;