Macrocyclic Pd(II) dithiolate complexes as catalysts in Heck reactions
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2016.11.085
Abstract: Abstract The supramolecular palladium dithiolate complexes, [Pd2(dppe)2{S(C6H4)nS}]2(OTf)4 and [Pd2(dppe)2(SCH2C6H4CH2S)]4(OTf)8 (dppe = 1,2-bis(diphenylphosphino)ethane) has been investigated as highly stable and robust catalysts in Heck C-C coupling reactions. The arylation of butyl acrylate and styrene with various aryl bromides… read more here.
Keywords: heck reactions; complexes catalysts; catalysts heck; dithiolate complexes ... See more keywords
Aromatic π-Components for Enantioselective Heck Reactions and Heck/Anion-Capture Domino Sequences.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.1c00781
Abstract: ConspectusOlefin functionalization represents one of the most important synthetic transformations in organic synthesis. Over the past decades, palladium-catalyzed enantioselective Heck reactions, and Heck/anion-capture domino sequences through olefin carbopalladation followed by termination of the resulting alkyl-Pd… read more here.
Keywords: heck; anion capture; heck anion; enantioselective heck ... See more keywords