Chain-end functionalization of living helical polyisocyanides through a Pd(ii)-mediated Sonogashira coupling reaction
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DOI: 10.1039/d1py00809a
Abstract: Various functional helical polymers were constructed through chain-end functionalization of living helical polyisocyanides through a Pd(ii)-mediated Sonogashira coupling reaction. read more here.
Keywords: chain end; polyisocyanides mediated; living helical; helical polyisocyanides ... See more keywords
Cobalt(III)-salen Decorated Stereoregular Optically Active Helical Polyisocyanides Enable Highly Effective Cooperative Asymmetric Catalysis toward Kinetic Resolution of Epoxides
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DOI: 10.1039/d3qi00384a
Abstract: Static one-handed helical polymers can serve as an ideal catalytic platform toward chiral synthesis. As a demonstration of helical polyisocyanides on asymmetric catalysis, we report a novel strategy to facilitate... read more here.
Keywords: cobalt iii; helical polyisocyanides; asymmetric catalysis; salen decorated ... See more keywords