High-resolution iron X-ray absorption spectroscopic and computational studies of non-heme diiron peroxo intermediates.
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DOI: 10.1016/j.jinorgbio.2019.110877
Abstract: Ferritin-like carboxylate-bridged non-heme diiron enzymes activate O2 for a variety of difficult reactions throughout nature. These reactions often begin by abstraction of hydrogen from strong CH bonds. The enzymes activate O2 at their diferrous cofactors… read more here.
Keywords: herfd xas; spectroscopy; non heme; peroxo ... See more keywords