Electrical, and Magnetic Characteristics of Homo- and Hetero-Bimetallic Macromolecular Complexes with π-Conjugated Imine-oxime Backbone
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-020-01805-1
Abstract: Seven homo- and hetero-bimetallic macromolecular complexes (BMCs) were prepared via an in-situ multi-step complexation reaction of Cu II , Ni II and Fe III metal centers with imine- oxime π-conjugated ditropic spacer (1,4-phenylene-bis(2,3-butanedeimineoxime, L 2−… read more here.
Keywords: bimetallic macromolecular; macromolecular complexes; electrical magnetic; homo hetero ... See more keywords
Hetero-Bimetallic Effect as a Route to Access Multinuclear Complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01466
Abstract: We report the synthesis of a key mononuclear intermediate complex based on a quinoid ligand and its further metalation to afford the corresponding hetero-bimetallic compound that revealed unique properties. An unprecedented hetero-bimetallic effect in coordination… read more here.
Keywords: bimetallic effect; chemistry; hetero bimetallic; ligand ... See more keywords
pH dependent binding in de novo hetero bimetallic coiled coils.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01568f
Abstract: Herein the first example of a bimetallic coiled coil featuring a lanthanide binding site is reported, opening opportunities to exploit the attractive NMR and photophysical properties of the lanthanides in multi metallo protein design. In… read more here.
Keywords: binding; hetero bimetallic; site; bimetallic coiled ... See more keywords
Novel hetero-bimetallic coordination polymer as a single source of highly dispersed Cu/Ni nanoparticles for efficient photocatalytic water splitting
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry frontiers"
DOI: 10.1039/c8qi00355f
Abstract: A new strategy for depositing highly dispersed Cu and Ni nanoparticles on the surface of TiO2 from a single source is demonstrated for photocatalytic hydrogen production. We used a newly synthesized cyanide-bridged hetero-bimetallic coordination polymer… read more here.
Keywords: single source; highly dispersed; hetero bimetallic; bimetallic coordination ... See more keywords
Folding of unstructured peptoids and formation of hetero-bimetallic peptoid complexes upon side-chain-to-metal coordination† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03616k
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c8sc03616k
Abstract: Metal ions initiate peptoids helicity that lead to positive allosteric cooperativity. read more here.
Keywords: folding unstructured; formation hetero; peptoids formation; metal ... See more keywords
An unprecedented hetero-bimetallic three-dimensional spin crossover coordination polymer based on the tetrahedral [Hg(SeCN)4]2- building block.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc01291e
Abstract: Self-assembly of octahedral FeII ions, trans-1,2-bis(4-pyridyl)ethane (bpe) bridging ligands and [Hg(XCN)4]2- (X = S (1), Se (2)) tetrahedral building blocks has afforded a new type of hetero-bimetallic HgII-FeII spin-crossover (SCO) 3D 6,4-connected coordination polymer (CP)… read more here.
Keywords: spin crossover; hetero bimetallic; coordination polymer; spin ... See more keywords
Hetero-bimetallic alkali titanosilicates [MOTi{OSi(OtBu)3}3]2 (M = Li-Cs) with terminal Ti-O- groups.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00939k
Abstract: The molecular titanosilicate [(tBuO3)3SiO]3TiNEt2 (1) was obtained from the reaction between silanol (tBuO3)3SiOH and titanium amide Ti(NEt2)4. The reaction of 1 with alkali metal hydroxides MOH (M = Li, Na, K, Rb, Cs) offers a… read more here.
Keywords: hetero bimetallic; moti osi; bimetallic alkali; titanosilicates moti ... See more keywords
Hetero-Bimetallic Ferrocene-Containing Zinc(II)-Terpyridyl-Based Metallomesogen: Structural and Electrochemical Characterization
Sign Up to like & getrecommendations! Published in 2023 at "Materials"
DOI: 10.3390/ma16051946
Abstract: The synthesis, as well as the mesomorphic and electrochemical properties, of a hetero-bimetallic coordination complex able to self-assemble into a columnar liquid crystalline phase is reported herein. The mesomorphic properties were investigated by polarized optical… read more here.
Keywords: terpyridyl based; containing zinc; hetero bimetallic; bimetallic ferrocene ... See more keywords