Photocatalytic C–H silylation of heteroarenes by using trialkylhydrosilanes† †Electronic supplementary information (ESI) available: Tables S1–S6, Scheme S1–S8, Fig. S1–S4, experimental procedures and characterization for all of the new compounds. See DOI: 10.1039/c9sc00046a
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c9sc00046a
Abstract: A distinctive visible light-promoted photocatalytic approach for the C–H silylation of heteroarenes by using trialkylhydrosilanes was developed. read more here.
Keywords: using trialkylhydrosilanes; heteroarenes using; trialkylhydrosilanes electronic; silylation heteroarenes ... See more keywords
Regioselective magnesiations of functionalized arenes and heteroarenes using TMP2Mg in hydrocarbons.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03856k
Abstract: We report the preparation of a new hydrocarbon-soluble magnesium amide TMP2Mg (TMP = 2,2,6,6-tetramethylpiperidyl). This base showed excellent properties for the regioselective magnesiation of various arenes and heteroarenes bearing ethyl esters and carbamates under very… read more here.
Keywords: magnesiations functionalized; regioselective magnesiations; arenes heteroarenes; heteroarenes using ... See more keywords