Nickel-Catalyzed Enantioselective Reductive Arylation and Heteroarylation of Aldimines via an Elementary 1,4-Addition.
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DOI: 10.1021/jacs.3c00548
Abstract: Nickel catalysts of chiral pyrox ligands promoted enantioselective reductive arylation and heteroarylation of aldimines, using directly (hetero)aryl halides and sulfonates. The catalytic arylation can also be conducted with crude aldimines generated from condensation of aldehydes… read more here.
Keywords: reductive arylation; arylation; enantioselective reductive; arylation heteroarylation ... See more keywords