Lanthanide-Incorporated Polyoxometalates Assembled from Mixed-Heteroatom-Oriented Three-Layered Cage Clusters.
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DOI: 10.1021/acs.inorgchem.2c02810
Abstract: Discovering innovative metal-oxo cluster materials with uncommon building blocks and exploiting their application potentiality are fairly challengeable. Here, we provide a novel type of lanthanide-incorporated polyoxometalates [H2N(CH3)2]10Na8H6{[Ln0.5/Na0.5(HGCA)(H2O)1.5]2[(BiO3)(SeO3)2W21O66]2}ยท36H2O [Ln = Eu3+ (1), Er3+ (2), H2GCA =… read more here.
Keywords: heteroatom; incorporated polyoxometalates; three layered; chemistry ... See more keywords