Pd-Catalyzed Dynamic Kinetic Asymmetric Cross-Coupling of Heterobiaryl Bromides with N-Tosylhydrazones
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DOI: 10.1021/acs.orglett.2c01355
Abstract: A dynamic kinetic asymmetric Pd-catalyzed cross-coupling reaction of heterobiaryl bromides with ketone N-tosylhydrazones for the synthesis of heterobiaryl styrenes is described. The combination of Pd(dba)2 as a precatalyst with a TADDOL-derived phosphoramidite ligand provides the… read more here.
Keywords: dynamic kinetic; heterobiaryl bromides; kinetic asymmetric; cross coupling ... See more keywords