Rhodium-Catalyzed Asymmetric Arylative Ring-Opening Reactions of Heterobicyclic Alkenes with Anilines.
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DOI: 10.1021/acs.orglett.7b03941
Abstract: Asymmetric arylative ring-opening reactions of heterobicyclic alkenes with anilines have been reported for the first time. A wide range of heterobicyclic alkenes, including azabenzonorbornadienes and oxabenzonorbornadienes, were well tolerated in the reaction with various anilines,… read more here.
Keywords: ring opening; heterobicyclic alkenes; arylative ring; asymmetric arylative ... See more keywords
RhIII-catalyzed annulation of N-methoxyindozamides with heterobicyclic alkenes towards indolo[3,2-c]heteroarenes
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DOI: 10.1080/00397911.2018.1465095
Abstract: Abstract A rhodium-catalyzed annulation protocol towards indolo[3,2-c]-1-azaanthraenes and successive treatment with different acids, which offered diverse indolo[3,2-c]-heteroarenes, were herein demonstrated. The transition metal-mediated system offered a direct and facile approach towards the heterocyclic compounds of… read more here.
Keywords: towards indolo; annulation; heterobicyclic alkenes; indolo heteroarenes ... See more keywords