H2 and carbon-heteroatom bond activation mediated by polarized heterobimetallic complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Coordination chemistry reviews"
DOI: 10.1016/j.ccr.2020.213765
Abstract: The field of heterobimetallic chemistry has rapidly expanded over the last decade. In addition to their interesting structural features, heterobimetallic structures have been found to facilitate a range of stoichiometric bond activations and catalytic processes.… read more here.
Keywords: chemistry; heterobimetallic complexes; carbon heteroatom; heteroatom bond ... See more keywords
Synthesis and characterization of (Ru(II), Co(III)) heterobimetallic complexes formed with a 1,10-phenanthroline based hydroxamic acid conjugate
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121265
Abstract: Abstract A novel ambidentate type hydroxamic acid derivative (phenhaH, 1) containing an (O,O) and a 1,10-phenantroline (phen) based (N,N) donoratom set together with its heterobimetallic complexes incorporating an octahedral [Co(4 N)]3+ (4 N = tris(2-aminoethyl)amine (tren) or tris(2-methylpyridyl)amine (tpa))… read more here.
Keywords: heterobimetallic complexes; hydroxamic acid; cym; characterization iii ... See more keywords
Cd(II)/Fe(III) heterobimetallic complexes with dien and cyanido ligands as precursors of ferrite-type oxides: Syntheses, crystal structures, thermal properties and identification of the oxides
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115101
Abstract: Abstract From the aqueous systems Cd(II) – dien – [Fe(CN)6]3-, where dien is 1,4,7-triazaheptane, two novel ionic complexes [Cd(dien)2]3[Fe(CN)6]2.3H2O (1) and NH4[Bu4N][Cd(dien)2]2[Fe(CN)6]2 (2) were prepared and characterized by spectroscopic (IR and UV-VIS) and EDX method.… read more here.
Keywords: cyanido ligands; crystal structures; complexes dien; heterobimetallic complexes ... See more keywords
Phosphine Ligand Binding and Catalytic Activity of Group 10-14 Heterobimetallic Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00229
Abstract: Heterobimetallic complexes have attracted much interest due to their broad range of structures and reactivities as well as unique catalytic abilities. Additionally, these complexes can be utilized as single-source precursors for the synthesis of binary… read more here.
Keywords: ligand binding; heterobimetallic complexes; ligand; group ... See more keywords
Formation of Heterobimetallic Complexes by Addition of d10-Metal Ions to [(Me3P)xM(2-C6F4PPh2)2] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00311
Abstract: Treatment of the bis(chelate) complexes trans-[M(κ2-2-C6F4PPh2)2] (trans-1M; M = Ni, Pt) and cis-[Pt(κ2-2-C6F4PPh2)2] (cis-1Pt) with equimolar amounts or excess of PMe3 solution gave complexes of the type [(Me3P)xM(2-C6F4PPh2)2] (x = 2: 2Ma, 2Mb x =… read more here.
Keywords: metal ions; heterobimetallic complexes; formation heterobimetallic; me3p c6f4pph2 ... See more keywords
Model Compounds for Intermediates and Transition States in Sonogashira and Negishi Coupling: d8-d10 Bonds in Large Heterobimetallic Complexes Are Weaker than Computational Chemistry Predicts.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01641
Abstract: We report an experimental study, with accompanying DFT calculations, on a series of heterobimetallic complexes with Pd(II) and Cu(I), Ag(I), or Au(I). The isolable pincer complexes are models for the intermediates and transition state for… read more here.
Keywords: heterobimetallic complexes; chemistry; sonogashira negishi; negishi coupling ... See more keywords
Ruthenium(ii) and palladium(ii) homo- and heterobimetallic complexes: synthesis, crystal structures, theoretical calculations and biological studies.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02353d
Abstract: Four Ru-Pd heterobimetallic complexes, each one in two different coordination modes (NNSS and NS) having metals connected by a binucleating dialkyldithiooxamidate [N(R)SC-CS(R)N] [R = methyl, ethyl, n-butyl and isopropyl], were prepared by reacting the monochelate… read more here.
Keywords: coordination; heterobimetallic complexes; homo heterobimetallic; crystal structures ... See more keywords
Lability of Ta-NHC adducts as a synthetic route towards heterobimetallic Ta/Rh complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt00344a
Abstract: We report the synthesis and characterization of a series of original tantalum/rhodium heterobimetallic species assembled by a bifunctional alkoxy-N-heterocyclic carbene (NHC) ligand platform (noted L). The heterotrimetallic [Ta(CH2tBu)(CHtBu)(μ-L)Rh2(COD)2Cl2]n, 2, and heterobimetallic [Ta(μ-L)(CHtBu)(CH2tBu)2Rh(COD)Cl], 4, complexes are… read more here.
Keywords: heterobimetallic complexes; synthetic route; nhc adducts; ch2tbu ... See more keywords
Possible Synthetic Approaches for Heterobimetallic Complexes by Using nNHC/tzNHC Heteroditopic Carbene Ligands
Sign Up to like & getrecommendations! Published in 2019 at "Molecules"
DOI: 10.3390/molecules24122305
Abstract: The synthesis of heterobimetallic complexes remains a synthetic challenge in the field of organometallic chemistry. A possible approach in this regard might be the use of a bidentate heteroditopic bis(carbene) ligand that combines an imidazol-2-ylidene… read more here.
Keywords: tznhc; possible synthetic; heterobimetallic complexes; carbene ... See more keywords
Heterobimetallic Ru(II)/M (M = Ag+, Cu2+, Pb2+) Complexes as Photosensitizers for Room-Temperature Gas Sensing
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27165058
Abstract: This work is devoted to the investigation of heterobimetallic Ru(II) complexes as photosensitizers for room-temperature photoactivated In2O3-based gas sensors. Nanocrystalline In2O3 was synthesized by the chemical precipitation method. The obtained In2O3 matrix has a single-phase… read more here.
Keywords: heterobimetallic complexes; spectroscopy; gas; room temperature ... See more keywords
Synergistic Catalysis in Heterobimetallic Complexes for Homogeneous Carbon Dioxide Hydrogenation
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28062574
Abstract: Two heterobimetallic Mo,M’ complexes (M’ = IrIII, RhIII) were synthesized and fully characterized. Their catalytic activity in homogeneous carbon dioxide hydrogenation to formate was studied. A pronounced synergistic effect between the two metals was found,… read more here.
Keywords: hydrogenation; heterobimetallic complexes; carbon dioxide; homogeneous carbon ... See more keywords