Heterobimetallic 21,23-dimetallaporphyrin: activation of metal-metal interactions within the porphyrinoid macrocycle.
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DOI: 10.1039/d3cc01367g
Abstract: Two core-modified porphyrins containing metal atoms, namely platinum(II) or platinum(IV) and rhodium(III), in place of two NH units, have been obtained by a post-synthetic modification of the 21,23-ditelluraporphyrin. The products of the tellurium-to-metal exchange, 21-platina-23-rhodaporphyrins,… read more here.
Keywords: dimetallaporphyrin activation; heterobimetallic dimetallaporphyrin; activation metal; metal ... See more keywords