Actinide Complexes Possessing Six-Membered N-Heterocyclic Iminato Moieties: Synthesis and Reactivity
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DOI: 10.1021/acs.organomet.7b00037
Abstract: A novel class of ligand systems possessing a six-membered N-heterocyclic iminato [perimidin-2-iminato (PrRN, where R = isopropyl, cycloheptyl)] moiety is introduced. The complexation of these ligands with early actinides (An = Th and U) results… read more here.
Keywords: heterocyclic iminato; six membered; possessing six; membered heterocyclic ... See more keywords
Remodeling of N-Heterocyclic Iminato Ligand Frameworks for the Facile Synthesis of Isoureas from Alcohols and Carbodiimides Promoted by Organoactinide (Th, U) Complexes
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DOI: 10.1021/acsomega.1c01836
Abstract: A new class of actinide complexes [(L)An(N{SiMe3}2)3] (An = Th or U) (Th1–Th3 and U1–U3) supported by highly nucleophilic seven-membered N-heterocyclic iminato ligands were synthesized and fully characterized by single-crystal X-ray diffraction. These complexes were… read more here.
Keywords: heterocyclic iminato; remodeling heterocyclic; ligand frameworks; iminato ligand ... See more keywords