(C4Me4)Co-containing triple-decker complexes with bridging heterocyclic ligands
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.06.025
Abstract: Abstract (C 4 Me 4 )Co-containing triple-decker complexes with bridging boron and phosphorus heterocyclic ligands [(C 4 Me 4 )Co(μ-η:η-L)MCp*] + ( 1 : M = Fe, L = C 5 H 5 BMe; 2 : M = Fe, L = C 4… read more here.
Keywords: containing triple; complexes bridging; decker complexes; triple decker ... See more keywords
Effects of Polyoxometalates on the Hydroxylation of N-Heterocyclic Ligands.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02702
Abstract: Four polyoxometalate (POM)-based Cu complexes with the hydroxylated pyridine analogue 3-(2-hydroxylpyrid-4-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl (btpo), H3{[Cu2(btpo)2](PW12O40)}·2H2O (1), H3{[Cu2(btpo)2](PMo12O40)}·2H2O (2), H2{[Cu2(btpo)2](SiW12O40)·SO4 (3), and H4{[Cu4(btpo)4](SiW12O40)}·8H2O (4), were synthesized hydrothermally under acid conditions. Single-crystal X-ray structural analysis reveals that 3-(pyrid-4-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl was… read more here.
Keywords: hydroxylation heterocyclic; btpo; cu2 btpo; polyoxometalates hydroxylation ... See more keywords
When is a Pyridine Not a Pyridine? Benzannulated N-Heterocyclic Ligands in Molecular Materials Chemistry
Sign Up to like & getrecommendations! Published in 2023 at "Canadian Journal of Chemistry"
DOI: 10.1139/cjc-2022-0314
Abstract: The C=N bond is a critical structural piece of many N-donor ligand scaffolds and is central to the properties and reactivity of important coordination complexes. For example, C=N units play a key role in the… read more here.
Keywords: pyridine pyridine; heterocyclic ligands; chemistry; pyridine ... See more keywords