N-Heterocyclic Silylene Coordinated Dialkyl Borenium Equivalent
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00687
Abstract: In an attempt to prepare the heavier analogue of NHC-stabilized borenium cation, we have prepared a silylene-coordinated borenium equivalent (1a), which can be viewed as a contact ion pair of borenium and triflate. The triflate… read more here.
Keywords: borenium; borenium equivalent; heterocyclic silylene; silylene ... See more keywords
Reactivity of an N-heterocyclic silylene with a 1,1'-ferrocenediyl backbone towards carbonyl compounds, including carbon suboxide.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc03947d
Abstract: Reactions of a silylene with a ketene and with carbon suboxide are reported, respectively leading to the first silaallene oxide and to a silylketene, whose reaction with water affords the first structurally characterised stable methyleneketene… read more here.
Keywords: carbon; carbon suboxide; heterocyclic silylene; silylene ferrocenediyl ... See more keywords