Substrate-Dependent Conformational Switch of the Noncubane [4Fe-4S] Cluster in Heterodisulfide Reductase HdrB.
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DOI: 10.1021/jacs.2c10885
Abstract: The noncubane [4Fe-4S] cluster identified in the active site of heterodisulfide reductase (HdrB) displays a unique geometry among Fe-S cofactors found in metalloproteins. Here we employ resonance Raman (RR) spectroscopy and density functional theory (DFT)… read more here.
Keywords: noncubane 4fe; reductase hdrb; cluster; 4fe cluster ... See more keywords