Heterogeneous Cobalt‐Catalyzed Direct N‐Formylation of Isoquinolines with CO2 and H2
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DOI: 10.1002/cctc.201601682
Abstract: Isoquinolines (IQs) are an abundant feedstock, and N‐formyl‐1,2,3,4‐tetrahydroisoquinolines (FTHIQs) are valuable fine chemicals and key intermediates. Herein, we report for the first time the Co0/ZnCl2‐catalyzed direct N‐formylation of IQs by using CO2 with H2 to… read more here.
Keywords: formylation; formylation isoquinolines; heterogeneous cobalt; cobalt catalyzed ... See more keywords
Heterogeneous Cobalt‐Catalyzed C−C Bond Cleavage in Alcohols to Carbonyl Compounds
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DOI: 10.1002/cctc.202100950
Abstract: Cobalt oxide hydrate (Co(OH)x) supported on metal oxides were prepared. The oxidative cleavage of C(OH)−C bond in alcohol was catalyzed by Co(OH)x/metal oxides using molecular oxygen as the oxidant, and the corresponding product was obtained… read more here.
Keywords: cleavage; bond; heterogeneous cobalt; cobalt catalyzed ... See more keywords
A CO2 photoreduction heterogeneous cobalt-based cocatalyst constructed via in situ electrostatic adsorption deposition.
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DOI: 10.1039/c9cc00744j
Abstract: Employing palygorskite (Pal) as a moderate alkaline regulator, herein we report the construction of a novel heterogeneous cobalt-based cocatalyst via an in situ electrostatic adsorption deposition process for its application to the photoreduction of CO2… read more here.
Keywords: adsorption; cobalt based; heterogeneous cobalt; situ electrostatic ... See more keywords