Molecular mechanism of heterogeneous supramolecular catalysis of metal-free cucurbituril solid for epoxide alcoholysis
Sign Up to like & getrecommendations! Published in 2019 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2019.01.021
Abstract: Abstract Heterogeneous and supramolecular catalysis are fundamental processes in chemistry. To understand the synergistic role between heterogeneous and supramolecular catalysis, the catalytic mechanism of cucurbituril solid for epoxide alcoholysis was investigated by performing density functional… read more here.
Keywords: supramolecular catalysis; cucurbituril solid; heterogeneous supramolecular; epoxide alcoholysis ... See more keywords
Heterogeneous Supramolecular Catalysis through Immobilization of Anionic M4L6 Assemblies on Cationic Polymers.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c09556
Abstract: Although most of the currently developed supramolecular catalysts that emulate enzymatic reactivity with unique selectivity and activity through specific host-guest interactions work under homogeneous conditions, enzymes in nature can operate under heterogeneous conditions as membrane-bound… read more here.
Keywords: catalysis immobilization; supramolecular catalysis; immobilization anionic; cluster ... See more keywords